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dehydrogenative coupling of silanes
The dehydrogenative coupling of silanes is a powerful technique of the formation of Si-Si bonds in disilanes, oligosilanes and long, silicon-based polymers. These reactions are Wurtz-type coupling processes, and they generally must be catalyzed, as the rate-determining step is the kinetically unfavourable dissociation of hydrogen from silicon. Luckily, there are numerous transition metal complexes that can catalyze reactions between a wide variety of silanes, whether they be primary, secondary or tertiary.
==Primary Silane==
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
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